A range of mono vinyl Ru(CH=CHC6H4R 4)(CO)(PPh3)Tp complexes have been obtained from the reaction of RuHCl(CO)(PPh3)3 with para substituted ethynylphenylenes, and KTp. (R = NO2, CO2Me, CN, Me and OMe). These complexes have been fully characterised spectroscopically, with molecular structures for Ru(CH=CHC6H4NO2 4)(CO)(PPh3)Tp, Ru(CH=CHC6H4CN 4)(CO)(PPh3)Tp, Ru(CH=CHC6H4CH3)(CO)(PPh3)Tp and Ru(CH=CHC6H4OMe 4)(CO)(PPh3)Tp being determined and analysed.
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